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Think of the water molecules as cars driving. In hot water, the molecules move very rapidly, while in cold water, they move very slow. Now view the freezing temperature as the brake system. Going from a higher temp. to a freezing temp. will cause the molecules to react like a speeding car slamming on it's brakes. The molecules slow down at a faster rate than as a moderate moving car, gently pressing the brakes.
Also, the byproduct of heat is already being released for the hot water, so using the energy to slow down the molecules comes naturally. For the cold water, energy that must be used to slow down the molecules is also warming the cold water (very minuscule, however still there).
Just my thoughts, comment if you please.
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